Unfortunately v2.14 won't help because it was just a rebuild and has no new features. We are working on a major overhaul of the MATH table that will address the font-specific problems.
In the meantime, you might want to look at
https://sourceforge.net/p/xetex/bugs/175/
and
https://sourceforge.net/p/xetex/bugs/173/
and the comments in the implementation of get_ot_math_kern() in
https://github.com/TeX-Live/texlive-source/blob/trunk/texk/web2c/xetexdir/XeTeXOTMath.cpp
Note especially comment (3) in the superscript branch.
Cheers,
David.